Beilstein J. Org. Chem.2011,7, 653–657, doi:10.3762/bjoc.7.77
bond. In addition, no byproducts derived from carbene coupling were observed.
Keywords: carbene insertion; copper catalysts; diazoacetates; gold catalysts; naphthalene functionalization; selectiveinsertion; Introduction
At the end of the nineteenth century, Buchner discovered [1] the thermal and
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Graphical Abstract
Scheme 1:
(a) The Buchner reaction of benzene and ethyl diazoacetate and (b) the Rh-catalyzed version. (c) Bo...